I wouldn't say zero but they won't do a ton.
The Bradford Bypass will relieve some pressure on the central 401 for example - rerouting traffic coming from Northern Ontario and Simcoe County wanting to go the the east end of the city (and downtown!) eastwards.
413 will similarly pull traffic going west.
Overall those numbers are pretty small though, and the traffic modelling for those highways corroborate that. The 413 and Bradford bypass have hugely beneficial traffic impacts but it's actually mostly from relieving more local traffic patterns in and around the municipalities they run through. New highways are good for corridors that don't already have good road connections like Kitchener-Hamilton, they aren't as good for relieving an existing route.
The cheapest and best way to fix congestion on a highway is widen that highway as it has a direct 1:1 impact for all trips on the corridor and is often cheaper than new corridors anyway - you need less land and often less new structures. There is a reason MTO opted to widen the 401 to Kitchener instead of building a 413 connection to create a second freeway link - it's cheaper and did a better job of actually reducing travel times.
A reminder of what MTO wants to build in the GGH over the next 25 years:
View attachment 710622
There are small handful of extra projects not on that map that MTO is building towards as well, like HOVs on the QEW from Oakville to Toronto.